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"pH & Total Alkalinity Problems"
pH is
always more important, but these factor go hand-in-hand.
The Pool & Spa Informational Website
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Important Pool Chemistry Factors
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The
topics of pH and total alkalinity are inter-related
and are key parameters (factors) in the
overall spa water chemistry.
pH is the relative acidity or alkalinity of the water. The pH scale
goes from 0 (most acidic) to 14 (most alkaline). A pH of 7.0 is neutral.
Ideally, spas and hot tubs should be maintained in the 7.2-7.8 range for a variety of
considerations: sanitizer effectiveness, bather comfort, corrosion, cloudy
water and scaling. Total alkalinity is a measurement of the total quantity
of alkaline materials present in the water. Low TA allows for rapid pH
fluctuations, makes pH control more difficult and can contribute to corrosion.
High TA makes pH adjustments more difficult and can be a contributing factor in
cloudy water and scaling. A range of 80-120 PPM is considered
optimum. The balancing of the overall water chemistry makes for greater
bather comfort, helps avoid problems and
is necessary to assure optimum spa water quality.
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testers require no color matching or look up charts and perform the
following tests: pH, Free & Total Chlorine, Bromine, Total Alkalinity,
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►
Battle Of pH and Total Alkalinity (TA)?
You sent me an email to look over your site. Loved it! Great!
I do have a question though, as always!! Even when I have my TA between 80
- 120 my pH constantly increases up to 8.0, this happens daily. I
try and gradually decrease the pH by adding acid in a bucket of water each day,
but no matter how carefully I do this my TA always drops. I find it much
easier, in my pool, to keep the TA low, about 40 - 50. My pH does not
bounce around so much and stays at the correct level of between 7.2 - 7.8.
My pool often gets a staining problem in summer and my local pool shop tells me
its because of the constantly increasing pH levels. I read in your
questions page that low TA can cause corrosion, and am now worried. I am
interested in your opinions and wonder if I just have an unusual pool.
Thanks.
Kelly H., Australia, 11/17/2007
Thanks for the
reply. It is more important to maintain a pH in the 7.2-7.8 range, than it
is to maintain a TA of 80-120 PPM. Your water probably contains some minerals,
other than bicarbonates and carbonates, that cause the buffering effect to be
higher than normal. Try and keep the pH in range. If you can do this
without great difficulty and without daily corrections and, if the water is
clear, there is no reason to do battle with the TA. The staining
could be due to algae: as the pH rises the chlorine effectiveness decreases and
that , in turn, can lead to a greater likelihood of algae growth. From
your letter it doesn't seem that you are having pH control problems, so I
suggest that you ignore the TA. The staining could, also, be due to dissolved
minerals: as the pH rises the solubility of many minerals decreases - another
reason to keep the pH in range. Adding a quality Mineral Treatment is
always a good idea, if minerals might be present. I guess you're getting
ready for summer. In sunny Florida, we are having the coldest weather in 8
months, but I love it. Enjoy the summer down under.
Sincerely. Alan Schuster, 11/17/2007
►
Color Vision Problems?
I don't seem to very good at
determining whether the pH color is orangish, orange-red or reddish. It
seems the same with strips or liquids. I may have a problem discerning
colors, but is there a simple solution?
Adam M., 6/24/2007
Not
everyone is adept at seeing small color differences and certain colors are worse
than others. The new
ColorQ PRO &
Water Analyzer can easily solve your
problem. It performs 7, pH, free and total chlorine, bromine, total
alkalinity, cyanuric acid and calcium hardness) of the common pool tests and is
all digital. No colors to match and no charts to look up. It is
reasonably priced and seems to be just what you're looking for. I
hope this will solve the problem.
Sincerely.
Alan Schuster, 6/24/2007
► pH & TA Reassurance?
I have a 22k pool with vinyl
liner. It is now clear with a TA of 140 and a pH of 7.0. I have
added 2 lbs then another 2 lbs of pH up with little or no change in
pH. Any help?
Don C., 4/16/2009
pH and TA are
interrelated. Raising the pH will raise the TA. In your case the high TA is
making pH adjustment difficult. However, once it is in range, it will remain
there for longer periods of time. pH is always more important and you need to
raise it to at least 7.2. Adjust the pH to 7.2-7.6, as needed.
There is no compelling reason to have to
lower the TA, once the pH is in range and there is no sign of scaling or cloudy
water. If
the calcium hardness is over 400 PPM, you might keep the pH closer to 7.2-7.4.
There's little point in trying to get both parameters in range, when
circumstances and nature are conspiring against you. Good luck.
Sincerely.
Alan Schuster, 4/16/2009
Alan, I did what you said and raised the pH to
7.3. The TA is now 240. My water is clear and looks good the
Chlorine is 2.0 Calcium hardness is around 200 ppm. I am scared with
the high TA, you are the only person that gives me this advice. My local
pool people demand that TA should not be above 120. I suppose I just need
some reassurance. Thanks.
Don, 4/18/2009
Nothing like
being out there on a limb. And did you notice that I am not trying to sell you
anything? There is something called the
Langelier Index: a predictor of scaling or corrosive tendencies of
water. Ideally water should fall within the -0.5 to +0.5 range. Your water
calculates out at +0.2. I agree that lowering the TA could be of benefit.
However, your water is clear, there is no signs of scaling or cloudy water and
Langelier Index is in range and, therefore, there is no
compelling reason to lower the TA.
High TA tends to keep the pH in place for longer
periods of time and, if the pH is optimum, that is a good thing!
pH is always more important.
Lowering the TA will lower the pH and that opens the door to corrosion and
irritation problems. Some might
suggest that you add acid to the pool. This will lower the TA, but it will
lower the pH, as well. You might end up with a "good" TA, but you will have a
low pH. The next step will be to raise the pH. Doing that will raise the TA.
In the end, you'll be out money and have water that is substantially the same.
You'll feel like a yo-yo. A TA range of
80-120 PPM is accepted as ideal. That means if you are lower, you should raise
it into this range. It doesn't necessarily mean, that if you are above this
range, you have to lower it, as this depends on other factors.
Your TA of 240 PPM is actually lower because you should be subtracting 30% or
the cyanuric acid reading form this test value. Ask the dealer, if he guarantees
success and that the chemicals will be free, if his instructions are followed
and both the pH and TA are not optimized? I suggest that
you avoid all use of calcium hypochlorite products, as this will increase the
Langelier Index. Right now you are OK, so long as the pH is 7.2-7.5. For
shock, use liquid chlorine, non-chlorine shock or lithium hypochlorite. Do not
use dichlor products, if you are using trichlor, as this will only speed up the
rise of the stabilizer level. I hope that I have helped to make my case.
Let me know how things turn out - either way!
Sincerely.
Alan Schuster, 4/19/2009
► Using Sodium TetraBorate?
I just can't get my pH and
total alkalinity on the same page. Either both are too high or the pH is
too low. It doesn't make sense to add acid and then add soda ash.
Have a suggestion?
Jeff H., 7/2/2004
Sometimes,
Nature conspires against proper pool chemistry, by having minerals present in
the water. pH is always more important and you should get it into the
7.2-7.6 range. If the TA is too high, it might not be a problem, so long
as the hardness is not over 400 PPM, the water is clear and there are no signs
of scaling. Otherwise, you might try adding acid and dropping the TA to
about 100 PPM. Your pH will be too low, at this point. Instead
of using soda ash to raise the pH, use sodium tetraborate. It will still
raise the pH, but will not contribute to the bicarbonate-carbonate content,
which is the basis of the TA test. I hope that this information is
helpful.
Sincerely.
Alan Schuster, 7/3/2004
►
pH & Total
Alkalinity Challenged?
Good morning. I am so
confused, I have an above ground pool, 10,000 gallons, pool looked real clear
and clean, my pH was low and for some unknown reason to me, I could not get the
pH up to par. So I took a water sample to the nearest pool supply store.
I was told that my total alkalinity was 250 PPM and the pH was 6.8 and I must
get the TA between 125-150 PPM, before trying to balance the pH. I added
dry acid and got the TA to 140 PPM. I have now added a total of 5 pounds
of pH increaser and it is still low and my pool is cloudy now. What major
effect does alkalinity have on the pool and it really necessary to keep it
between 125-150 PPM, if the pH and chlorine are balanced? Do you have any
idea what is wrong and how I can correct this problem? Is it OK to shock
the pool while I am trying to raise the pH? It show I have 1.5 PPM
chlorine in the pool, but I have not shocked it for a while and I think that I
may need to. Thank you.
Clifford P., 9/17/2005
I'll bet that
you are feeling like a yo yo?
THERE IS NO COMPELLING REASON TO HAVE TO KEEP THE TA BETWEEN 125-150 PPM, IF THE
pH IS CORRECT, THE WATER IS CLEAR AND THERE ARE NO SIGNS OF CALCIUM SCALE
FORMATION! Adding
the acid lowered the TA and lowered the pH. Adding the pH increaser raised
the pH and the TA. You accomplished very little. I suggest that you
add pH increaser and raise the pH to 7.2-7.6. If at this point, the water
is clear and there are no signs of scale formation, leave the TA alone.
The higher TA will help stabilize the pH for even longer periods of time.
The only time a high TA will cause a problem is if the calcium hardness level is
too high. A calcium hardness level over 400 PPM, might require you to
lower the pH to 7.2-7.4. You can add shock at any time. Bear in mind
that shock products can affect the pH, depending upon which product is used.
I hope that this information will prove helpful. Let me know how it turns
out for you.
Sincerely.
Alan Schuster, 9/17/2005
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► Not Playing Yo Yo?
Thank you for your reply to my question. I have now resolved the problem
first by several partial drainings, which reduced the alkalinity from the
200 range to just above 100. Then I discovered that I could use sodium
tetra borate to raise the pH. This actually does raise pH significantly,
BUT has very little effect on alkalinity. Using acid to take both
readings way down and then introducing the sodium tetraborate brought the
levels to where I wanted them.
John D., 8/24/2007
At least you were not playing yo
yo with the pH and TA. The partial drainings lowered the cyanuric acid and,
possibly, the hardness level. These contribute directly or indirectly to the TA
reading. Unless these parameters were high, you might have accomplished the
same effect without the draining. Using sodium tetraborate will raise the
pH and not contribute as to the bicarbonate-carbonate alkalinity. To
get a truer fix on the TA, subtract 30% of the cyanuric acid reading from the TA
reading. I am glad that I have been helpful in solving the problem.
Sincerely. Alan Schuster, 8/25/2007
►
High TA And Green
Water?
Hi, Alan.
We just opened our pool and added fresh city water a few days ago. Our total
alkalinity is off the charts – around 400. I keep reading conflicting
instructions on how much Muriatic Acid to add and how often. One website said
not to add more that 1 Qt per 10,000 gallons in a 24 hour time period. (Our
pool is about 16,000). Another website said to add 3 gallons to get it down
to the optimal range, but didn’t say how much to add and how often. So far,
we’ve added about 1.5 gallons at a slow pace for the last 2 days, but it’s
still 400! The pH is registering about 7.0 right now. Also, can we add
chlorine? We haven’t added any yet and there is no free chlorine left from the
winter. (The pool is green). If it’s OK to add chlorine, should we use shock
or liquid chlorine?
Kari B., 4/16/2004
A TA of 400 is
too high. However, a pH of 7.0 is borderline low. You have green
water and algae and that is the first step that you need to take. When you
solve that problem, you should address the TA and the pH. By all means use
liquid chlorine. It will raise the pH slightly and may be all that is
needed to correct that parameter. Once the algae is gone, add a dose of a
blue clarifier to help remove dead algae and debris. Adjust the pH to
7.2-7.6. If the water is clear and
there is no sign of scaling (due to high calcium hardness levels), there is no
compelling reason for you to have to reduce the TA. NONE!
That is unless you want to acid, only to have to add pH increaser soon after.
It is not always possible to get them both in balance and pH is always more
important! My advice on high TA
has always been to add one pint of acid daily, until the TA is in range or the
pH reaches a low of 7.2 and at that point -- stop!
I am not saying that TA is unimportant. A high TA will require more
chemicals to adjust the pH. However, if the pH is optimum, a high TA will
keep it there for longer periods of time and that is a good thing. If the water
is clear, there is no need to keep adding acid and ending up with a low pH and
having to boost it up. I suggest that you test the calcium
hardness. With a higher TA, you want the level to be not higher than 200
PPM, in order to avoid scaling. If your calcium hardness is above 200 PPM,
you might want to lower the TA over time, as I have suggested it be done. I
suggest that you refrain from using chlorine or shock containing calcium
hypochlorite. I hope that you will find the information helpful.
Sincerely.
Alan Schuster, 4/16/2004
►
How Much Acid Is Too
Much?
When our pool gets out of
balance, my husband thinks it must be solved in one day and puts in up to 3/4
gallon acid in one day. My pool repair people think this is excessive. How
much acid is too much to be good for people and pool?
Catherine, 4/16/2005
The important
consideration is, what is the pH? Even if I knew how big your pool is, I
could not answer the question. If you add acid and end up with a pH below
7.2, the amount was excessive. If the pH ends up at 7.2-7.6, it was the
correct amount. If the pH remains high, more needs to be added.
Acid will react with alkaline materials in
the pool water and only the pH reading determines, if too much has been added.
If your pool is being maintained on liquid chlorine, depending upon how much
chlorine is added weekly, a certain amount of acid will probably be required.
The amount depends upon your pool size, circumstances and water chemistry.
A word of advice. You can always add
more -- you can't take out!
I hope that I have been helpful.
Sincerely.
Alan Schuster, 4/17/2005
►
Worried About Adding Too Much
Acid?
I've added what I think is too
much Muriatic acid in my salt water pool. My test asked for 1 quart for my
20,000 gallon pool and I put 2.5 quarts. Should I be concerned? and do I need
to drain my pool? Thank you for your time.
Jessica, 9/29/2006
Unless
your pH has dropped below 7.2, you have not added too much acid. You
add acid to lower the pH. If too much is added (the pH is under 7.2), all
you need to do is add some soda ash to raise the pH into the 7.2-7.6 range.
Salt
chlorine generators tend to cause the pH
to rise over time, so adding acid will become a regular occurrence, as will the
testing of the pH and chlorine. I hope that I have put your mind at ease.
Sincerely.
Alan Schuster, 9/29/2006
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►
Is The High TA
Causing Problems?
Alan. Nice informative
website. I think I've read most of the information you have given regarding
high TA and not to worry if the pH is okay and I don't have a problem with
cloudiness. However, our water calcium hardness is high to start (city water)
and I have noticed shades of grey forming, starting at the bottom of the deep
end and a little here and there around the pool. Based on what I have read and
been told, scale formation. Depressing, since I'd just had the pool resurfaced
last year. My question would be to confirm that I need to lower the TA and if
there's anything I can do to get rid of the grey shades. Also lowering the TA
will lower the pH, do I simply lower the TA regardless of how low the pH
becomes and then raise the pH after? Thanks.
Rich L., 3/3/2004
The shades of
gray could be scale or it could be a mineral problem.
Have
the calcium hardness level checked. Testing for iron and copper is
suggested. If, the calcium hardness is less than 400 PPM, scale
formation is either unlikely or easily corrected by lowering the pH and/or the
TA. High TA is a problem, if it leads to scale formation. You can do
several things: drop the pH into the acid ranges, add a calcium
sequestering treatment and slowly restore the pH or add acid and drop the pH to
7.2, add a calcium sequestering agent and keep the pH at this low point until
the deposits are gone. Your city water may be hard, but it still may not
be excessively high in calcium. In either case, I would refrain from all
use of calcium hypochlorite products, as it can only add to the problem. I
hope that this information will prove helpful.
Sincerely.
Alan Schuster, 3/3/2004
►
Low pH and High TA?
I know that the pH and
alkalinity are generally linked to each other - in that if the TA is high then
the pH usually follows. But, I am wondering why sometimes the pH is low
and the TA can be high (like a pH 6.8 and a TA at 180 PPM). Have you had
any experience on how this phenomenon occurs? And also - the best way to
remedy the situation. Thanks very much.
Kent K., 6/27/2006
When you have a
situation as you are describing it is likely because the total alkalinity is not
being based solely on the typical bicarbonate-carbonate buffering system.
Cyanuric acid and other naturally occurring minerals can produce an alkalinity
reading without necessarily stabilizing the pH in the optimum range.
pH is always the more
important parameter. If the water is clear and there are no signs of
scaling, there is no compelling reason to have to maintain a TA in the 80-120
PPM. Adjust the pH
to optimum. If the TA is too high (as expected in this case) and the water
is clear and there is no scaling present, all that the high TA will do is to
help stabilize the pH even more than usual. And that is not a bad
thing! Trying to balance both parameters, in every pool, will likely
lead to frustration and credibility gaps, in many instances. I hope that I
have provided some good advice.
Sincerely.
Alan Schuster, 6/27/2003
Thanks very much, Alan.
Working in the profession myself, I can say I both appreciate and respect your
knowledge and pool maintenance tips.
Good to hear your
advice. Best regards.
Kent K., 6/27/2006
►
Low pH Causes
Burning Eyes?
We have a "L" shaped
pool 40X20X16. The water was crystal clear, steps and skimmers were pure
as white. I took a water sample to pool supply place and they said there was no
Alkalinity in the water and the pH was very low. Told me to purchase 45lbs
of Alkalinity increaser and 10 lbs of pH Increaser. Put to Alkalinity in
about 6 hours prior to the pH increaser. Alkalinity went to 155, pH
6.2. They told me to add 5 lbs more or pH increaser. The steps are
"BROWN"! and so is the skimmers. And the water is cloudy.
As soon an I add a little Muriatic Acid, the steps turn white again
instantly! Should I believe the tester of my water or my eyes. It
seems to me I should have left the water alone, except when I was vacuuming it a
couple of weeks ago, I had an itch in my eye and I think I got a little pool
water on my hand then I rubbed my eye. It burned my eye for more than 5
hours after that. I almost went to the Emergency room. What do you think
is my problem?
Bob G., 6/16/2004
Of course you
believe your eyes. They're burning because the pH is too low.
A low pH reading makes the chlorine more irritating and aggressive. It
also tends to keep minerals in solution. The brown stains are probably
iron and other minerals that precipitated, as the pH was raised.
You
have no choice about raising the pH.
I suggest that you have the water tested for iron. Get the steps white and
then add 3-4 doses of a quality mineral treatment, before you attempt to raise
the pH. Allow about 6 hours of circulation before attempting to restore the
pH. Add pH Increaser only. TA increaser is probably not going to be
required. Do not
swim with the pH at low levels.
Good luck and I hope that I have been helpful
Sincerely.
Alan Schuster, 6/16/2004
►
What To Do About
High TA?
Alan, my inground pool is
less than 4 months old. Construction is concrete with white marcite plaster
finish. I use auto controllers and a UV light system for better water
conditions. I have recently run into a problem with pH and alkalinity. This
particular pool is 30 x 50 and indoors with a dehumidification system to
ensure proper indoor pool climate. When I perform daily/hourly pH and
alkalinity tests, the controller is 7.5 pH, my pH water test is 7.5. This
is good. However, when I perform the alkalinity test, I get readings that are
50 to 80 points per/million too high. If I add acid to lower the TA, then my
pH drops and then end up adding dense soda ash or sodium bicarbonate to
increase pH. I use liquid chlorine (sodium hypochlorite) for sanitation, and
I know it adds alkalinity. How do I get my pH / TA back in balance?
Perplexed, 9/30/2003 Not one word in your letter about cloudy water. That
leads me to believe that your water is clear and there are no other problems
with the pool water. That being the case, there is absolutely no reason to
have to lower the TA. Adjust the pH to optimum and if the TA is too high,
leave it be! Unless you are having cloudy water or calcium scale
problems, the higher TA will cause no problems. Lowering it will prove
elusive and accomplish little. If in the future, if there are cloudy water
conditions or calcium scaling, the problem can be addressed. In the
meantime, the higher TA will act to better stabilize the pH. I hope the
advice will help.
Sincerely. Alan Schuster, 9/30/2003
►
Bicarb Or Soda Ash?
I would like to know the difference between soda
ash and sodium bicarbonate? I have been using sodium bicarbonate for
raising pH. Do I also need to add soda ash to raise Alkalinity?
Jeff C., 4/27/2007
Rule #1: pH is always more important the
TA. Always! You seem to have gotten things backwards.
Sodium bicarbonate (baking soda) should only be used to raise the TA, as
it has only a slight effect on the pH. Sodium carbonate (soda ash) is only used
to raise the pH, as it is much more effective than sodium bicarbonate.
Soda ash will also raise the TA, to an extent. If you use soda ash to
raise the TA, you will probably end up with much too high a pH. I hope
that this information is helpful.
Sincerely.
Alan Schuster, 4/27/2007
►
Total
Alkalinity And Stabilizer?
I have been in the pool/spa business for about 4
years and have become a little confused about the relationship between
conditioner (cyanuric acid) and total alkalinity. The more sophisticated
chemical testing software programs we use to analysis water all make a 30%
adjustment for cyanuric acid, in the total alkalinity readings. But, few
if any body every talks about it on the many informational web sites out
there, including yours. Can you give me a detailed understanding of this
relationship, and if it should really be taken into consideration when testing
for TA?
Stan C., 12/14/2003
Good
question!
The
total alkalinity test measures the presence of all materials, dissolved in
the water, that are more alkaline than a pH of approximately 4.5. In
swimming pool water this includes not only the carbonates and bicarbonates, but
silicates, phosphates and cyanurates as well. Cyanuric acid is a weak acid
and in swimming pool water forms various cyanurates, which are weakly alkaline.
Typically, other than the carbonates and bicarbonates, only the cyanurates are
present in a high concentration. Chlorides and sulfates do not have a
significant effect upon the pH or TA. Inasmuch as the TA test picks up all
of the alkaline materials, it does not distinguish between carbonates, bicarbonates and cyanurates. The purpose, of the carbonates and
bicarbonates, is to create a buffer that will help stabilize the pH in the
7.2-7.8 range and they are ideally suited for this purpose.
Cyanurates,
on the other hand, will register on the TA test, but are not chemically
well-suited to act as a pH buffer in the 7.2-7.8 range. High levels of
cyanuric acid will inflate the true carbonate/bicarbonate total alkalinity test
readings and, perhaps, give a false impression of properly buffered water.
To eliminate this error, 30% of the cyanuric acid reading should be deducted
from the total alkalinity reading, in order to approximate the true
carbonate/bicarbonate alkalinity. The important thing is to consider the
ability of the pool to maintain a stable pH, without the need for frequent pH
adjustment. In hard water situations and in areas with high TDS, it may be
preferable to keep a lower carbonate/bicarbonate TA because of the possibility
of scaling and cloudy water conditions. I hope that I was able to explain
the theory behind the chemistry.
Sincerely.
Alan Schuster, 12/16/2003
►
Too Much
Total Alkalinity (TA)?
My total alkalinity
is usually over 180 PPM. My pH is good and the water looks great. My problem is
that every time I try and lower the total alkalinity to below 120 PPM, I end up
with a pH that is too low. Raising the pH back up, ends up raising the total
alkalinity. I feel as if I'm being yo yo'ed. Any suggestions?
Steve T., San
Antonio, TX, 7/23/2006
It is more
important to maintain a proper pH, than it is to maintain a TA of 80-120 PPM.
Minerals that may occur naturally, in your water, might be contributing to this
phenomenon. There is no compelling reason for you to have to lower
the TA: your pH is good and the water is clear. Stop
worrying about the TA, unless there are signs of cloudiness, the appearance of
calcium scale or other water chemistry problems. Leave the worrying to those
with very low TA, that are unable to keep the pH from bouncing. Enjoy the
summer.
Sincerely.
Alan Schuster, 7/23/2006
►
High
Total Alkalinity?
I refilled my spa
last week and I just had my water tested and the results follow: pH 7.4,
TA 155, calcium hardness 178, bromine 3.5 PPM. The water looks perfect.
The dealer suggested that I add some Total Alkalinity Decreaser. Should I
add the product? I'm not sure that it's necessary. Please let me
know what to do. Thanks.
J. N., Albany, GA,
5/30/2005
Your TA is
marginally above the ideal of 80-120 PPM. However, your pH is ideal. the
calcium hardness is very good and the water is "perfect."
A higher TA means that your pH will remain in place for even longer periods
of time and, with a pH of 7.4, and that is a good thing!
In your
particular case there is absolutely no reason to adjust the TA. It would
be different, if your calcium hardness was too high, or the pH was too high or
if the water was not "perfect." I hope that I've made the point.
Enjoy the spa.
Sincerely.
Alan Schuster, 5/30/2005
►
Acid Demand Test?
Hello, when I am doing an acid demand test, what product
am I adding when it is out of balance? Thanks.
Darryl, 4/3/2004
An acid demand test is performed, when the pH is too high,
in order to determine how much pH reducer (sodium bisulfate) is required.
The results are probably in pounds per 10,000 gallons of pool water.
Remember, you can always add more - you can't take out! Hope I've been
helpful.
Sincerely. Alan Schuster, 4/3/2004
►
Too
Little Total Alkalinity (TA)?
Can I use pH
increaser to raise my total alkalinity? My readings are around 50 PPM and
the pH of the water is 6.9. Needing some help.
Jim I., Jamesport,
NY, 7/6/2004
No, you should
not use pH increasers to raise the TA. To do so could raise the pH too
high and that will require more adjustment in the opposite direction.
Raise the TA, using a Total Alkalinity increaser and then test the pH. If
too low, add some pH increaser. In all likelihood, adjusting the TA
will correct the pH and bring it into the ideal range. Enjoy the season.
Sincerely.
Alan Schuster, 7/6/2004
►
Low TA & Proper pH?
Since you are a professional in the field I
have to ask you this question. I know there are some questions posted about low
total alkalinity and pH. I am an inspector for swimming pools, and know the
consequences of high and low alkalinity. The total alkalinity is 40-50 (for the
past few months), but perfect pH (7.2) and FAC (>0.5 ppm). In our regulation it
states that the total alkalinity must be at least 80 ppm. The operator said he
always adds sodium bicarbonate to raise the total alkalinity but it always
lowers to the present values. You said it might be do to mineral content. In
your professional opinion should he try adjusting the tot alkalinity (which it
will always lower) or keep it the way it is. Thanks for any feedback.
Troy S., 4/28/2005
The pH is at
the lower limit. The low TA makes it easier for the pH to fluctuate and
that is not desirable. All that should be necessary is for the TA to be
raised with sodium bicarbonate. As it is added, the pH will rise slightly.
Keep adding the bicarbonate, until the TA reaches 80 or the pH reaches
7.6. At that point stop. The type of chlorine that is being used may
account for the lowering of the TA and the pH of 7.2. I hope that I have
been helpful.
Sincerely.
Alan Schuster, 4/28/2005
►
High Total
Alkalinity?
The info
on how the alkalinity reading is impacted by the cyanuric acid in the pool was
very helpful and as I understand the formula, one should subtract a third of the
cyanuric level from the total alkalinity reading. Is this correct? The
question I have is about my testing of alkalinity. I followed the
instructions and find that my reading is 170. I had had my water tested at
my pool supply store and the computer says that my reading is 89 after the
cyanuric level is considered. My cyanuric level is 70. This is a bit
high however I live in Houston, TX and I understand the heat levels require a
higher cyanuric level. Any idea why I get such a high reading when I test?
I drop the acid demand in slowly and swirl the water between each drop and wait
for the water to chance from blue to clear as I count each drop. My water
hardness is 280. Thank you for any advice you can offer.
T.C.,
Houston, TX, 4/7/2003
If your
cyanuric acid
level is 70 PPM, it is quite appropriate for your situation. This
would contribute 20-25 PPM to the total alkalinity reading. Your TA
reading of 170 PPM and the store's net reading of 89 PPM do not
agree. One of them is wrong! If your calcium hardness is 280 PPM,
it is likely that the TA is not as low as 79 PPM. All I can suggest is
that you verify the test results with another water sample. I hope that I
have been helpful.
Sincerely. Alan
Schuster, 4/7/2003
► Dealer Suggested
Maintaining A Lower pH?
What a great site, it has already given me a lot
of help. Last summer when I took a water sample in to the pool shop I
though the pH was fine but I was advised to lower it. All summer they told
me to keep the pH a bit lower than the usual 7.2. I never got a full
explanation, as to why, but they seemed to say it was because of the extreme
heat in the Australian summer. Do you know of any reason why pH should ever be
kept slightly below the normal recommenced range. At present I have it is
in the normal range and it looks fine.
Chris, Australia, 1/15/2009
If your TA
and/or hardness were high, lowering the pH could help assure that the calcium
does not precipitate or cause scaling. Most manufacturers that utilize copper
ionization, as part of the sanitizing method, prefer a slightly low pH.
However, low pH readings below 7.0 can cause corrosion of the copper in the
heater and will make chlorine more irritating, but it will make the chlorine
more effective. The high summer temps might have prompted the
recommendation. You might ask the dealer, for the reason, as I do not have
all the facts, of your situation. I hope that this will prove
helpful.
Sincerely.
Alan Schuster, 1/16/2006
►
Why Not A
Low pH?
If chlorine works
better at lower pH readings, why not keep the pH lower than 7.2-7.6?
Anonymous,
6/2/2004
Chlorine does
work better at a pH below 7.2. However, there are consequences that will
result. Corrosion can present a problem below 7.0. As the pH falls
below 7.2, chlorine can become increasingly more aggressive and irritating.
The pH of the eye fluid is 7.6 and, as you move further away, discomfort can
increase. I hope that I have answered the question.
Sincerely.
Alan Schuster, 6/2/2004
►
Muriatic Acid Or
Sulfuric Acid?
What are the advantages/disadvantages of muriatic vs. sulfuric acid for
pH balance in pools. These pools have salt based chlorination systems.
Thanks. Regards.
Pat T., Tucson, AZ, 2/12/2004
Sulfuric acid has nearly 3 times the pH neutralizing
power of muriatic (hydrochloric acid). It lowers the TA, more
aggressively, than muriatic acid, but the pH will drop as well. However, it is far more
dangerous to handle and, in my opinion, should not be offered for use in
swimming pools. So far as the
salt
chlorination system is concerned,
there is no advantage or disadvantage. Did you know that, if you add
sulfuric acid to an equal amount of water, the temperature of the solution rises
to above the boiling point of water? Stick with the muriatic acid or sodium
bisulfate (granular pH reducer), as there is no compelling reason to have to use
sulfuric acid. I hope that you'll find the
advice worth following.
Sincerely. Alan Schuster,
2/12/2004
Thanks Alan. The reason I am asking
is I have installed several acid dispensing systems, using metering pumps, for
my neighbors recently. One of them has been using sulfuric acid rather
than muriatic. I bought muriatic for him and want to explain the differences
to him. Three of us have salt based chlorination systems in my neighborhood
and all require constant acid-about two cups per day for a 15,000 gal pool.
They also require about 5 pounds of sodium bicarbonate weekly to keep the
total alkalinity at about 110. The pools are all over a year old and are made
of an aggregate finish, which is common in our area. I wonder if our acid
usage will decline, if we forget about total alkalinity and just let that go
where it may and just keep the pH at the correct level. Do you have any
experience with salt based chlorination systems requiring chemicals like
this? We live in Tucson, AZ. Thanks. Alan, your insight is always
very helpful. Regards.
Pat T., Tucson, AZ., 2/13/2004
I directed
the question to a leading manufacturer of
salt chlorinating systems. The recommendation is to use muriatic acid. Sulfuric acid is
not something that is safe to handle. Muriatic acid may not be pleasant,
but it is far safer. Good luck and I hope that I have been helpful.
Sincerely. Alan Schuster, 2/13/2004
► Dry Acid Or
Muriatic Acid?
If I were to use a
liquid acid (instead of dry acid) to reduce pH, is there a difference
between using muriatic and dry acid? I seem to recall reading something
that pool dry acid would be less likely to reduce TA as much as muriatic.
Is that true?
Martin, 4/4/2007
The two chemicals have exactly the
same effect on pH and TA, when you allow for differences in their form.
Three pounds of the dry acid (sodium bisulfate) has about the same pH
lowering and TA lowering strength as one-liter (just over 1-quart) of
muriatic acid (hydrochloric acid). The dry acid probably costs
more, but is easier to handle, less apt to spill and lacks the noxious fumes
of the liquid acid. I hope that this clarifies the issue.
Sincerely. Alan Schuster, 4/4/2007
►
What Is Soda Ash?
Exactly what is soda ash?
Please reply. Thank you.
Gaye S., 4/22/2005
Soda ash is
sodium carbonate and is the chemicals used to raise the pH of a swimming pool
or spa. It is not the same as baking soda, which is sodium bicarbonate and is
used to raise the total alkalinity. For more information on this and other
swimming pool terms, please visit the website's
Glossary of Pool & Spa Terms.
I hope that I have been helpful.
Sincerely.
Alan Schuster, 4/22/2005
►
Using Carbon Dioxide To Lower pH?
I’m new to
pools, but as purchasing coordinator for a retirement community, I am getting
involved. I am told that CO2
can be used as an effective pH reducer. My question is how does CO2
react to cause this drop in pH. Any information you can
afford
would be greatly appreciated.
Bill K.,
Lincolnshire, IL, 4/4/2005
Carbon dioxide or
CO 2
dissolves in water forming carbonic acid. It is a weak acid and will lower
the pH. It is not simply added to the pool. It will require special
feeders and is not very cost effective or efficient. It's main advantage
is probably the safety issue. Most pools of your type rely on
muriatic acid for pH reduction. It can be used with a metering system and
is very cost effective. In either case, at any given pH the water is
indistinguishable. I hope that I have been of assistance.
Sincerely.
Alan Schuster, 4/4/2005
►
Low TA
And A Good pH?
Recently, I refilled
an above ground pool (approx 12000 gallons) after a liner replacement. I
had the water tested and was told that everything is OK, except for the total
alkalinity, which is a little low at 60. If that is the case, do I have to
raise the alkalinity to 100, as suggested. Thank you.
Fred R., Nashua, NH,
7/12/2004
It is not etched
in stone that you have to raise the Total Alkalinity. However, a better
question would be "should you raise the TA" and the answer is YES.
The purpose of keeping your TA, around 100 PPM, is to help stabilize the
pH and avoid rapid changes in pH, as routine maintenance chemicals are added.
Ultimately, the higher TA should make the pool water chemistry easier to
maintain. About 6-7 pounds of total alkalinity increaser chemical would be
required, to raise your pool from 60 PPM to 100 PPM. I'm a believer in
correcting low TA. It's your choice. Have a good season.
Sincerely.
Alan Schuster, 7/13/2004
►
Conflicting Results?
Dear Alan, I really like your
website. I do have a question on test strips and alkalinity. Can something in
the water make alkalinity not read on a test strip? I am in the pool business
and I have this pool that when I use a test strip to test alkalinity it comes up
in the 0-40 category. I know this is inaccurate because I added bicarb to
the swimming pool and got a 100 reading with test drops. Any information you can
supply me with will be a pleasure. Thank You.
Kevin, 5/30/2007
It's nothing
as mysterious as something in the water. One of the testers is not
functioning properly or is being misused. Double check the directions.
Based on the fact that you added something to raise the TA, I would suspect that
the test strips are not reading properly. The most likely cause is
excessive heat or exposure to moisture (wet fingers) or chemicals. It is
bad technique to remove a test strip with wet fingers. Have you tried
another package of
test strips? The product,
based on my own experience is suitably accurate and has good shelf-life.
You need to verify the test result, by using different test materials or
chemicals. I'm sure that you'll find the culprit. If you would like
to consider a step up in water testing, the
ColorQ PRO 7
Water Analyzer, would be an ideal solution. It is all
digital, requires no color matching, eliminates all guesswork or look up charts.
I hope that this information is helpful.
Sincerely.
Alan Schuster, 5/30/2007
►
Salt Chlorinator &
High pH?
Thanks so much for your web
site! We installed a Salt Chlorinator about 1 year into owning an in
ground pool (plaster sides). We previously used liquid Chlorine and tablets
from an in line tablet dispenser. Now we have a great chlorine reading,
but the pH is always high. I was told to add acid in the deep end, to lower the
alkalinity, and I did get the alkalinity down to 100 at one time, but then it
just bumped back up again. I am adding about 3/4 gal of acid in our 23,000 gal
pool per week to keep the ph in balance. This seems like a lot of acid and,
frankly, I think the pool was easier to maintain when it was on the in line
tablet dispenser. One other thing. The pool company said that the city
water could be raising the pH, but I turned off the auto-fill for the last
couple of weeks and still have the same problem. What do you think?
Is it normal to add this much acid? Is there anything I can do to keep the
pH down? Why does the pH go up? Thanks very much.
Mark, 4/16/2005
Salt chlorinators
can tend to cause the pH to rise, because of the chemical decomposition of the
salt. However, the plaster walls are probably making a contribution, as
well. I suggest that you just add acid, as needed, and keep the pH a bit
under 7.8. Don't concern yourself with the TA, just the pH. Other
than this, your maintenance will be simple. Before, you had to handle,
store and add tablets and liquid chlorine and adjust the pH. Prolonged use
of the stabilized chlorine tablets would have quickly boosted the stabilizer
level, to a point where a partial water replacement would have been necessary.
This is no longer a problem: present or future! And did I mention
that there is much less sensation of chlorine being present because the odorous
byproducts are destroyed, as water passes through the cell?
Salt chlorinators are not completely work-free, but,
as I see it, they are a lot better than adding chlorine the old fashioned way.
I hope that I have been helpful.
Sincerely.
Alan Schuster, 4/16/2005
►
Constant High
pH Problem?
I have a problem keeping my pH level in line. It is always high. I am always adding acid. I have the calcium
hardness checked quarterly and it is usually ok. The pool surface (Marcite) is approx. 9 years old. I am getting some blue-green stains (etching?) and
am considering acid washing the pool. I am in South Florida. Is it normal to always be adding
muriatic acid to the pool? Will an acid wash clean up the stains?
I have a heater. I primarily just use liquid chlorine and occasionally,
in the summer, I will add tabs as well.
Thanks.
John S., Wellington, FL,
5/12/2004
The liquid chlorine has a very high pH and it is entirely normal for you to have to add acid on a regular basis. There is no reason for your calcium hardness to change appreciably considering the sanitizer being used in the pool. The blue-green stain could be due to copper corrosion from the heater. This is likely, if the tablets are placed in the skimmer or there is no check valve between the chlorinator and the heater or the chlorinator is placed before the heater. I hope that I have been of assistance.
Sincerely.
Alan Schuster, 5/12/2004
► The Color Purple?
Sometimes when I run a pH test,
I get a purple color that looks like the pH is through the roof. I know
that it couldn't have risen that quickly. Is the tester bad or am I doing
something wrong?
Adam S., Cary, NC, 7/23/2006
Most likely you
are using bromine or have added a sodium bromide product. This means
bromine is present in the water and, if the concentration is very high, it could
interfere with the pH test. Under these conditions this purple color has
nothing to do with the actual pH. To avoid this problem, add a
drop of chlorine neutralizer test solution (sodium thiosulfate) to the sample
before testing. It will discharge or lower the bromine level. Some
pH testers are better able to perform properly, in the presence of bromine.
I hope this helps explain the problem.
Sincerely.
Alan Schuster, 7/24/2006
►
Low Total Alkalinity
And A Stable pH?
About 2 weeks ago, after
having changed my water, I added an ozonator & mineral purifier (Silver).
Since then my pH has remained rock stable at 7.4 and the water is always
crystal clear & without odor. The calcium hardness is approximately 100.
Everything seems great except my TA is only 30. You answered a similar
question where the TA was high, but I do not know if the response is different
if the reading is low. Assuming the pH remains stable & the water is not
cloudy, is the low TA a concern?
Rick L., 5/21/2004
A low TA and a stable pH are
almost a contradiction. With a TA of 30 PPM, the pH should be bouncing
around, especially in a vinyl pool. In a gunite pool, it would be
totally unexpected. A proper pH is always more important. I
suggest that you have the water tested for pH, TA and calcium hardness by a
dealer and compare it with your own results. A TA reading of 30 PPM is
subject to much greater inaccuracies than higher readings. The proof
will be in the numbers.
Sincerely.
Alan Schuster, 5/21/2004
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